Listar por autor "Gil-Negrete, José M."
Mostrando ítems 1-4 de 4
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Reactividad de organometálicos de Indio(iii) con sistemas benzoheterocíclicos
Gil-Negrete, José M. (2014)[Resumen]En este trabajo de fin de máster se estudió la reactividad de varios compuestos benzoheterocíclicos con reactivos triorganoíndicos bajo catálisis con complejos de níquel y bajo activaci ... -
Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions
Gil-Negrete, José M.; Pérez Sestelo, José; Sarandeses, Luis A. (Royal Society of Chemistry, 2018-02-11)[Abstract] Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R3In(DMAP) complexes are obtained from the corresponding solution of R3In in ... -
Transition-metal-free cross-coupling of indium organometallics with chromene and isochroman acetals mediated by BF3·OEt2
Gil-Negrete, José M.; Pérez Sestelo, José; Sarandeses, Luis A. (American Chemical Society, 2016)[Abstract] A transition-metal-free coupling of triorganoindium reagents with benzopyranyl acetals mediated by a Lewis acid has been developed. The reaction of R3In with chromene and isochroman acetals in the presence of ... -
Triorganoindium reagents in cross-coupling reactions: transition-metal-free reactions with benzopyranyl acetals and tetrahydroisoquinolines and solid-stable organometallics
Gil-Negrete, José M. (2019)[Abstract] This Thesis presents the development of a new transition-metal-free coupling reaction of triorganoindium reagents with chromene and isochroman acetals under BF3·OEt2 activation. This reaction allows the synthesis ...